This morning, I was greeted by this headline:
“Physicists turn liquid into solid using electric field”
To most people, this may evoke a thoughtful, “Huh. Neat.” But to me, it evoked something more along the lines of, “HOLY CRAP I TOTALLY CALLED THAT”. I started keeping a personal design notebook a few years ago to write down ideas I had, problems I was working on, designs, questions, things like that. On one of those pages, I wrote this about a year and a half ago when I was taking Physics II:

I think I was taking chemistry at the same time, and I began to wonder about messing with the dipole moment in a water molecule with an electric field. Specifically, could you make some sort of crystal by lining the molecules up in a lattice? I looked for publications on the topic, and all I could find was some random paper on the benefits of exposing your bread dough to an electric field (yeah, I don’t know either). I remember asking my professor about my idea. He didn’t really know the answer, and told me to try to calculate the forces on the molecules classically to see what would happen. Now that I’m taking electromagnetics, I know that it is not at all that simple. Which is why the guys in this paper used a simulator.
There are surprisingly few differences between what I was thinking about at the time and what the scientists at Tech did. They used formamide instead of water, since formamide has about twice the dipole moment of water. But sure enough, they found that by increasing the field enough, you can get a crystalline structure that is actually a phase change. It’s called electrocrystallization. It has been known for quite some time that electric fields can affect polarized molecules in macroscopic ways, since observations were made showing that raindrops near lightning changed shape and became long and skinny.

Now, there are a few caveats to these results. First of all, for the effect to happen, you have to have a very strong electric field (1.5 Volts per nanometer). However, the normal dielectric breakdown of most materials is below that by like two orders of magnitude. For a few exotic materials though, it’s not too far above the dielectric breakdown (it’s only about 3 times that of PVC). Even once you’ve dealt with the breakdown problem, I’m still not sure what the practical uses of something that changes state based on a giant electric field. But it’s still an interesting result.
So while I didn’t get a chance to pursue my idea very far back in Physics II, I learned two things. First, I was (pretty) right. And second, it was a good question. Their paper is going to be on the cover of The Journal of Physical Chemistry. I’m hopeful that if I keep trying to ask good questions, one day I’ll hit on something pretty interesting and get a chance to work on it before anyone else.